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南开2019年代表性论文

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 楼主| 发表于 2019-3-25 21:03:08 | 显示全部楼层
元素有机化学研究所李正名院士ANGEWANDTE,通讯作者:叶萌春、李正名
Angewandte Chemie, First published: 19 March 2019,DOI:10.1002/ange.201902607
https://onlinelibrary.wiley.com/doi/10.1002/ange.201902607

Ligand-Promoted Fe(III)-Catalyzed Hydrofluorination of Alkenes
Yongtao Xie, Peng-Wei Sun, Yuxin Li, Siwei Wang, Mengchun Ye*, Zhengming Li*

Dedicated to 100th anniversary of Nankai University

Abstract: An iron-catalyzed hydrofluorination of unactivated alkenes has been developed. The use of multi-dentate ligand and fluorination reagent (NFSI) proved to be critical for this reaction, affording various fluorinated compounds in up to 94% yield.

Y. Xie, P.-W. Sun, Y. Li, S. Wang, M. Ye, Z. Li
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071 (China)
E-mail: mcye@nankai.edu.cn, nkzml@vip.163.com
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 楼主| 发表于 2019-3-25 21:03:24 | 显示全部楼层
光电子薄膜器件与技术研究所张晓丹研究员通讯Nano Energy,通讯作者:Jinghai Yang,张晓丹
Nano Energy, In press, accepted manuscript, A vailable online 19 March 2019, 10.1016/j.nanoen.2019.03.059
https://www.sciencedirect.com/sc ... i/S221128551930254X

Toward ultra-thin and omnidirectional perovskite solar cells: Concurrent improvement in conversion efficiency by employing light-trapping and recrystallizing treatment
Fengyou Wang ace, Yuhong Zhang a, Meifang Yang a, Lin Fan ac, Lili Yang ac, Yingrui Sui ac, Jinghai Yang acd*, Xiaodan Zhang b*
a Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Changchun, 130103, China
b Institute of Photoelectronic Thin Film Devices and Technology of Nankai University, Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Renewable Energy Conversion and Storage Center, Tianjin, 300071, China
c National Demonstration Center for Experimental Physics Education, Jilin Normal University, Siping, 136000, China
d Si Ping Hong Zui University Science Park, Siping, 136000, China
e Key Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, 130103, China
*jhyang1@jlnu.edu.cn
*xdzhang@nankai.edu.cn
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 楼主| 发表于 2019-3-25 21:03:43 | 显示全部楼层
化学院陈军院士课题组ANGEWANDTE,通讯作者:牛志强研究员
Angew. Chem. Int. Ed.,DOI:10.1002/anie.201902679,First published: 20 March 2019
https://onlinelibrary.wiley.com/doi/10.1002/anie.201902679

Reversible Oxygen Redox Chemistry in Aqueous Zinc-Ion Batteries
Fang Wan,[a] Yan Zhang,[a] Linlin Zhang,[a] Daobin Liu,[ b] Changda Wang,[ b] Li Song,[ b] Zhiqiang Niu,*[a] and Jun Chen[a]
Dedicated to 100th anniversary of Nankai University

[a] Dr. F. Wan, Y. Zhang, Dr. L. Zhang, Prof. Z. Niu, Prof. J. Chen
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University,Tianjin, 300071, P. R. China
E-mail: zqniu@nankail.edu.cn
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 楼主| 发表于 2019-3-25 21:04:01 | 显示全部楼层
物理学院通讯作者+并列一作NAT COMMUN,通讯作者:Lixin Zhang等
Nature Communications, volume 10, Article number: 1348 (2019),Published: 22 March 2019
https://www.nature.com/articles/s41467-019-09269-9

Boundary activated hydrogen evolution reaction on monolayer MoS2
Jianqi Zhu1,2, Zhi-Chang Wang3, Huijia Dai4, Qinqin Wang1,5, Rong Yang1,5, Hua Yu1, Mengzhou Liao1,5, Jing Zhang1, Wei Chen1, Zheng Wei1,5, Na Li1,5, Luojun Du1, Dongxia Shi1,5, Wenlong Wang1,5, Lixin Zhang4, Ying Jiang 3,6,7 & Guangyu Zhang1,5,6,8

1 CAS Key Laboratory of Nanoscale Physics and Devices, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.
2 School of Physics and Electronic Engineering, Sichuan Normal University, Chengdu, Sichuan 610101, China.
3 International Center for Quantum Materials, School of Physics, Peking University, Beijing 100871, China.
4 School of Physics, Nankai University, Tianjin 300071, China.
5 School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100190, China.
6 Collaborative Innovation Center of Quantum Matter, Beijing 100190, China.
7 CAS Center for Excellence in Topological Quantum Computation, University of Chinese Academy of Sciences, Beijing 100190, PR China.
8 Beijing Key Laboratory for Nanomaterials and Nanodevices, Beijing 100190, China.
These authors contributed equally: Jianqi Zhu, Zhi-Chang Wang, Huijia Dai. Correspondence and requests for materials should be addressed to R.Y. (email: ryang@iphy.ac.cn) or to L.Z. (email: lxzhang@nankai.edu.cn) or to Y.J. (email: yjiang@pku.edu.cn) or to
G.Z. (email: gyzhang@iphy.ac.cn)



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 楼主| 发表于 2019-3-25 21:04:20 | 显示全部楼层
生命科学学院丁丹研究员Advanced Materials,通讯作者:丁丹,Bing Yang,Yongming Zhang,Wang Zhang Yuan
Advanced Materials Early View First published: 25 March 2019 10.1002/adma.201807222
https://onlinelibrary.wiley.com/doi/10.1002/adma.201807222
共同通讯+并列一作

Achieving Persistent, Efficient, and Robust Room-Temperature Phosphorescence from Pure Organics for Versatile Applications
Zihan He#, Heqi Gao#, Shitong Zhang, Shuyuan Zheng, Yunzhong Wang, Zihao Zhao, Dan Ding,* Bing Yang,* Yongming Zhang,* and Wang Zhang Yuan*
Z. He, Dr. S. Zheng, Y. Wang, Z. Zhao, Prof. Y. Zhang, Prof. W. Z. Yuan
School of Chemistry and Chemical Engineering, Shanghai Key Lab of Electrical Insulation and Thermal Aging, Shanghai Electrochemical Energy Devices Research Center, Shanghai Jiao Tong University, Shanghai 200240, China
E-mail: ymzhang@sjtu.edu.cn; wzhyuan@sjtu.edu.cn
H. Gao, Prof. D. Ding
State Key Laboratory of Medicinal Chemical Biology, Key Laboratory of Bioactive Materials, Ministry of Education, College of Life Sciences, Nankai University, Tianjin 300071, China
E-mail: dingd@nankai.edu.cn
Dr. S. Zhang, Prof. B. Yang
State Key Laboratory of Supramolecular Structures and Materials, College of Chemistry, Jilin University, Changchun 130012, China
E-mail: yangbing@jlu.edu.cn
#Z.H. and H.G. contributed equally to this work.
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 楼主| 发表于 2019-3-25 21:04:37 | 显示全部楼层
材料科学与工程学院朱剑研究员Advanced Materials,通讯作者:朱剑
Advanced Materials Early View First published: 25 March 2019 10.1002/adma.201806480
https://onlinelibrary.wiley.com/doi/10.1002/adma.201806480

Self-Limiting Assembly Approaches for Nanoadditive Manufacturing of Electronic Thin Films and Devices
Zhao Wang#, Yu Kang#, Sanchuan Zhao#, and Jian Zhu*
Z. Wang, Y. Kang, S. Zhao, Prof. J. Zhu
School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, P. R. China
E-mail: zj@nankai.edu.cn
Prof. J. Zhu
Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry & Tianjin Key Laboratory for Rare Earth Materials and Applications, Nankai University, Tianjin 300350, P. R. China
#Z.W., Y.K., and S.C.Z. contributed equally to this work.



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 楼主| 发表于 2019-3-30 20:05:26 | 显示全部楼层
化学学院陈永胜课题组Advanced Materials,通讯作者:万相见,陈永胜

Advanced Materials Early View First published: 25 March 2019 10.1002/adma.201804723

https://onlinelibrary.wiley.com/doi/10.1002/adma.201804723




A Tandem Organic Solar Cell with PCE of 14.52% Employing Subcells with the Same Polymer Donor and Two Absorption Complementary Acceptors

Lingxian Meng#, Yuan-Qiu-Qiang Yi#, Xiangjian Wan,* Yamin Zhang, Xin Ke, Bin Kan, Yanbo Wang, Ruoxi Xia, Hin-Lap Yip, Chenxi Li, and Yongsheng Chen*

L. Meng, Y.-Q.-Q. Yi, Dr. X. Wan, Y. Zhang, X. Ke, B. Kan, Y. Wang, Prof. C. Li, Prof. Y. Chen

The Key Laboratory of Functional Polymer Materials, State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology, College of Chemistry, Nankai University, Tianjin 300071, China

E-mail: xjwan@nankai.edu.cn; yschen99@nankai.edu.cn

R. Xia, Prof. H.-L. Yip

State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China

L.M. and Y.-Q.-Q.Y. contributed equally to this work.




Abstract

The tandem structure is an efficient way to simultaneously tackle absorption and thermalization losses of the single junction solar cells. In this work, a high‐performance tandem organic solar cell (OSC) using two subcells with the same donor poly[(2,6‐(4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)‐benzo[1,2‐b:4,5‐b′]dithiophene))‐alt‐(5,5‐(1′,3′‐di‐2‐thienyl‐5′,7′‐bis(2‐ethylhexyl)benzo[1′,2′‐c:4′,5′‐c′]dithiophene‐4,8‐dione))] (PBDB‐T) and two acceptors, F‐M and 2,9‐bis(2‐methylene‐(3(1,1‐dicyanomethylene)benz[f ]indanone))7,12‐dihydro‐(4,4,10,10‐tetrakis(4‐hexylphenyl)‐5,11‐diocthylthieno[3′,2′:4,5]cyclopenta[1,2‐b]thieno[2″,3″:3′,4′]cyclopenta[1′,2′:4,5]thieno[2,3‐f][1]benzothiophene (NNBDT), with complementary absorptions is demonstrated. The two subcells show high Voc with value of 0.99 V for the front cell and 0.86 V for the rear cell, which is the prerequisite for obtaining high Voc of their series‐connected tandem device. Although there is much absorption overlap for the subcells, a decent Jsc of the tandem cell is still obtained owing to the complementary absorption of the two acceptors in a wide range. With systematic device optimizations, a best power conversion efficiency of 14.52% is achieved for the tandem device, with a high Voc of 1.82 V, a notable FF of 74.7%, and a decent Jsc of 10.68 mA cm−2. This work demonstrates a promising strategy of fabricating high‐efficiency tandem OSCs through elaborate selection of the active layer materials in each subcell and tradeoff of the Voc and Jsc of the tandem cells.
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 楼主| 发表于 2019-3-30 20:05:43 | 显示全部楼层
药学院和药物化学生物学国家重点实验室刘遵峰教授Advanced Functional Materials,通讯作者:刘遵峰
Advanced Functional Materials Early View First published: 25 March 2019 10.1002/adfm.201808995
https://onlinelibrary.wiley.com/doi/10.1002/adfm.201808995

Photothermal Bimorph Actuators with In-Built Cooler for Light Mills, Frequency Switches, and Soft Robots
Jingjing Li, Rui Zhang, Linlin Mou, Monica Jung de Andrade, Xiaoyu Hu, Kaiqing Yu, Jinkun Sun, Tianjiao Jia, Yuanyuan Dou, Hong Chen, Shaoli Fang, Dong Qian, and Zunfeng Liu*
J. Li, L. Mou, X. Hu, K. Yu, J. Sun, T. Jia, Y. Dou, Dr. Z. Liu
State Key Laboratory of Medicinal Chemical Biology, Key Laboratory of Functional Polymer Materials, College of Pharmacy, Nankai University, Tianjin 300071, China
E-mail: liuzunfeng@nankai.edu.cn
R. Zhang, Prof. D. Qian
Department of Mechanical Engineering, University of Texas at Dallas, Richardson, TX 75080, USA
Dr. M. Jung de Andrade, Dr. S. Fang
Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Richardson, TX 75080, USA
Prof. H. Chen
School of Materials Science and Energy Engineering, Foshan University, Foshan 528325, China
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 楼主| 发表于 2019-3-30 20:06:02 | 显示全部楼层
电子信息与光学工程学院向东课题组Light: Science & Applications,通讯作者:Bingqian Xu,Takhee Lee,向东
Light: Science & Applications volume 8, Article number: 34 (2019) 10.1038/s41377-019-0144-z
https://www.nature.com/articles/s41377-019-0144-z

Atomic switches of metallic point contacts by plasmonic heating
Weiqiang Zhang, Hongshuang Liu, Jinsheng Lu, Lifa Ni, Haitao Liu, Qiang Li, Min Qiu, Bingqian Xu*, Takhee Lee*, Zhikai Zhao, Xianghui Wang, Maoning Wang, Tao Wang, Andreas Offenh?usser, Dirk Mayer, Wang-Taek Hwang & Dong Xiang*
Affiliations
Tianjin Key Laboratory of Optoelectronic Sensor and Sensing Network Technology, Key Laboratory of Optical Information Science and Technology, Institute of Modern Optics, College of Electronic Information and Optical Engineering, Nankai University, 300350, Tianjin, China
Weiqiang Zhang, Hongshuang Liu, Lifa Ni, Haitao Liu, Bingqian Xu, Zhikai Zhao, Xianghui Wang, Maoning Wang & Dong Xiang
State Key Laboratory of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, 310027, Hangzhou, China
Jinsheng Lu, Qiang Li & Min Qiu
College of Engineering, University of Georgia, Athens, GA, 30602, USA
Bingqian Xu
Department of Physics and Astronomy, and Institute of Applied Physics, Seoul National University, Seoul, 08826, Korea
Takhee Lee & Wang-Taek Hwang
Institute of Materials Research and Engineering, A*STAR, 2 Fusionopolis Way, Innovis, Singapore, 138634, Singapore
Tao Wang
Institute of Complex Systems, ICS-8, Bioelectronics, Research Center Juelich and JARA Fundamentals of Future Information Technology, Jülich, 52425, Germany
Andreas Offenh?usser & Dirk Mayer
*Correspondence to Bingqian Xu or Takhee Lee or Dong Xiang.
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 楼主| 发表于 2019-3-30 20:06:31 | 显示全部楼层
化学学院陈军院士课题组Angewandte Chemie International Edition,通讯作者:陈军
Angewandte Chemie International Edition Accepted Articles First published: 27 March 2019 10.1002/anie.201902185
https://onlinelibrary.wiley.com/doi/10.1002/anie.201902185

Cyclohexanehexone with ultrahigh capacity as cathode materials for lithium-ion batteries
Yong Lu, Xuesen Hou, Licheng Miao, Lin Li, Ruijuan Shi, Luojia Liu, and Jun Chen*
Dedicated to the 100th anniversary of Nankai University

Dr. Y. Lu, Dr. X. Hou, Dr. L. Miao, Dr. L. Li, Dr. R. Shi, Dr. L. Liu, Prof. J. Chen
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin 300071, China
*E-mail: chenabc@nankai.edu.cn
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 楼主| 发表于 2019-3-30 20:06:53 | 显示全部楼层
生命科学学院曹雪涛院士课题组Nature Reviews Immunology(IF=41.982),通讯作者:张迁,曹雪涛
Nature Reviews Immunology (2019) 10.1038/s41577-019-0151-6
https://www.nature.com/articles/s41577-019-0151-6

Epigenetic regulation of the innate immune response to infection
Qian Zhang* & Xuetao Cao*
Affiliations
College of Life Science, Nankai University, Tianjin, China
Qian Zhang & Xuetao Cao
National Key Laboratory of Medical Immunology & Institute of Immunology, Second Military Medical University, Shanghai, China
Qian Zhang & Xuetao Cao
Department of Immunology & Center for Immunotherapy, Institute of Basic Medical Sciences, Peking Union Medical College, Chinese Academy of Medical Sciences, Beijing, China
Correspondence to Qian Zhang or Xuetao Cao.
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 楼主| 发表于 2019-3-30 20:07:12 | 显示全部楼层
物理科学学院Phys. Rev. Lett.,通讯作者:Daniel Leykam,许京军,陈志刚
Phys. Rev. Lett. 122, 123903 (2019) - Published 29 March 2019
https://journals.aps.org/prl/abs ... sRevLett.122.123903


Valley Vortex States and Degeneracy Lifting via Photonic Higher-Band Excitation

Daohong Song1,2, Daniel Leykam3,*, Jing Su1, Xiuying Liu1, Liqin Tang1, Sheng Liu4, Jianlin Zhao4, Nikolaos K. Efremidis5, Jingjun Xu1,2,†, and Zhigang Chen1,2,6,‡

1The MOE Key Laboratory of Weak-Light Nonlinear Photonics, and TEDA Applied Physics Institute and School of Physics, Nankai University, Tianjin 300457, China
2Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan, Shanxi 030006, China
3Center for Theoretical Physics of Complex Systems, Institute for Basic Science, Daejeon 34126, Republic of Korea
4The Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education and School of Science, Northwestern Polytechnical University, Xi’an 710072, China
5Department of Mathematics and Applied Mathematics, University of Crete, 70013 Heraklion, Crete, Greece
6Department of Physics and Astronomy, San Francisco State University, San Francisco, California 94132, USA

*Corresponding author. dleykam@ibs.re.kr
†Corresponding author. jjxu@nankai.edu.cn
‡Corresponding author. zgchen@nankai.edu.cn

ABSTRACT

We demonstrate valley-dependent vortex generation in photonic graphene. Without breaking inversion symmetry, the excitation of two valleys leads to the formation of an optical vortex upon Bragg reflection to the third equivalent valley, with its chirality determined by the valley degree of freedom. Vortex-antivortex pairs with valley-dependent topological charge flipping are also observed and corroborated by numerical simulations. Furthermore, we develop a three-band effective Hamiltonian model to describe the dynamics of the coupled valleys and find that the commonly used two-band model is not sufficient to explain the observed vortex degeneracy lifting. Such valley-polarized vortex states arise from high-band excitation without a synthetic-field-induced gap opening. Our results from a photonic setting may provide insight for the study of valley contrasting and Berry-phase-mediated topological phenomena in other systems.
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 楼主| 发表于 2019-3-30 20:34:13 | 显示全部楼层
生命科学学院丁丹研究员Advanced Materials,通讯作者:丁丹
Advanced Materials Early View First published: 29 March 2019 10.1002/adma.201806331
https://onlinelibrary.wiley.com/doi/10.1002/adma.201806331



Regulating the Photophysical Property of Organic/Polymer Optical Agents for Promoted Cancer Phototheranostics
Chao Chen#, Hanlin Ou#, Ruihua Liu, and Dan Ding*
State Key Laboratory of Medicinal Chemical Biology, Key Laboratory of Bioactive Materials, Ministry of Education and College of Life Sciences, Nankai University, Tianjin 300071, China
*E-mail: dingd@nankai.edu.cn
#C.C. and H.O. contributed equally to this work.

Abstract

On the basis of the Jablonski diagram, the photophysical properties of optical agents are highly associated with biomedical function and efficacy. Herein, the focus is on organic/polymer optical agents and the recent progress in the main strategies for regulating their photophysical properties to achieve superior cancer diagnosis/phototheranostics applications are highlighted. Both the approaches of nanoengineering and molecular design, which can lead to optimized effectiveness of required biomedical function, are discussed.
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 楼主| 发表于 2019-4-6 15:57:19 | 显示全部楼层
化学学院陈军院士课题组ADVANCED MATERIALS, 通讯作者:程方益研究员
ADVANCED MATERIALS, First published: 01 April 2019, DOI:10.1002/adma.201806326

https://onlinelibrary.wiley.com/doi/10.1002/adma.201806326

Self-Supported Transition-Metal-Based Electrocatalysts for Hydrogen and Oxygen Evolution
Hongming Sun, Zhenhua Yan, Fangming Liu, Wence Xu, Fangyi Cheng,* and Jun Chen

Dr. H. Sun, Dr. Z. Yan, F. Liu, Dr. W. Xu, Prof. F. Cheng, Prof. J. Chen
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Renewable Energy Conversion and Storage Center, Nankai University, Tianjin 300071, China
E-mail: fycheng@nankai.edu.cn

Abstract

Electrochemical water splitting is a promising technology for sustainable conversion, storage, and transport of hydrogen energy. Searching for earth‐abundant hydrogen/oxygen evolution reaction (HER/OER) electrocatalysts with high activity and durability to replace noble‐metal‐based catalysts plays paramount importance in the scalable application of water electrolysis. A freestanding electrode architecture is highly attractive as compared to the conventional coated powdery form because of enhanced kinetics and stability. Herein, recent progress in developing transition‐metal‐based HER/OER electrocatalytic materials is reviewed with selected examples of chalcogenides, phosphides, carbides, nitrides, alloys, phosphates, oxides, hydroxides, and oxyhydroxides. Focusing on self‐supported electrodes, the latest advances in their structural design, controllable synthesis, mechanistic understanding, and strategies for performance enhancement are presented. Remaining challenges and future perspectives for the further development of self‐supported electrocatalysts are also discussed.
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 楼主| 发表于 2019-4-6 15:57:37 | 显示全部楼层
化学学院分析科学研究中心陈朗星教授ANGEWANDTE,与北京大学合作,通讯作者:陈朗星、徐东升
Angew. Chem. Int. Ed.,  DOI:10.1002/anie.201900658, First published: 02 April 2019|

https://onlinelibrary.wiley.com/doi/10.1002/anie.201900658

Stable and Highly Efficient Photocatalysis with Lead-Free Double-Perovskite of Cs2AgBiBr6

Zhenzhen Zhanga, b, Yongqi Liangb, Hanlin Huangb, Xingyi Liub, Qi Lib, Langxing Chena*, Dongsheng Xub*

[a] Z. Zhang, Prof. L. Chen
Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071, China
E-mail: lxchen@nankai.edu.cn
[b ] Y. Liang, H. Huang, X. Liu, Q. Li, Prof. D. Xu
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail:dsxu@pku.edu.cn

Abstract

Composition engineering of halide perovskite allows the tunability of the bandgap over a wide range so that photons can be effectively harvested, which is of critical importance for increasing the efficiency of photocatalysis under sunlight. However, the poor stability and the low photocatalytic activity of halide perovskites are preventing these defect‐tolerant materials from wide applications in photocatalysis. Here, an alcohol based photocatalytic system for dye degradation with high stability is demonstrated for double perovskite of Cs2AgBiBr6. The reaction rate on Cs2AgBiBr6 is comparable to that on CdS, a model inorganic semiconductor photocatalyst. The fact of fast reaction between free radical and dye molecules indicates the unique catalytic properties of Cs2AgBiBr6 surface. Deposition of metal clusters onto Cs2AgBiBr6 effectively further enhances the photocatalytic activity. Although the stability (five consecutive photocatalytic cycles without obvious decrease of efficiency) requires further improvements, our results indicate the significant potential of Cs2AgBiBr6 based photocatalysis.
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 楼主| 发表于 2019-4-6 15:57:54 | 显示全部楼层
材料科学与工程学院梁嘉杰课题组Advanced Materials,通讯作者:梁嘉杰
Advanced Materials Early View First published: 03 April 2019 10.1002/adma.201805864
https://onlinelibrary.wiley.com/doi/10.1002/adma.201805864

Recent Development of Printed Micro-Supercapacitors: Printable Materials, Printing Technologies, and Perspectives
Hongpeng Li and Jiajie Liang*
H. Li, Prof. J. Liang
School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, P. R. China
E-mail: liang0909@nankai.edu.cn
Prof. J. Liang
Key Laboratory of Functional Polymer Materials of Ministry of Education, College of Chemistry, Nankai University, Tianjin 300350, P. R. China
Prof. J. Liang
Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300350, P. R. China
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 楼主| 发表于 2019-4-6 15:58:13 | 显示全部楼层
环境科学与工程学院鞠美庭教授Applied Catalysis B: Environmental,通讯作者:鞠美庭
Applied Catalysis B: Environmental, In press, accepted manuscript, A-vailable online 3 April 2019, 10.1016/j.apcatb.2019.04.003
https://www.sciencedirect.com/sc ... i/S0926337319303194

Efficient catalytic conversion of glucose into 5-hydroxymethylfurfural by aluminum oxide in ionic liquid
Qidong Hou, Meinan Zhen, Weizun Li, Le Liu, Jinpeng Liu, Shiqiu Zhang, Yifan Nie, Chuanyunlong Bai, Xinyu Bai, Meiting Ju*
Tianjin Engineering Research Center of Biomass Solid Waste Resources Technology, College of Environmental Science and Engineering, Nankai University, Tianjin, 300350, PR China
*jumeit@nankai.edu.cn

Abstract
Conversion of biomass-derived glucose to 5-hydroxymethylfurfural (HMF) is an important step for valorizing lignocellulosic biomass. In conventional reaction systems such as aqueous or water-organic solvent biphasic system, degradation of the formed HMF and other intermediates into undesired products is inevitable due to the presence of Brønsted acid, limiting HMF production efficiency. Here, we develop a novel reaction system consisting of heterogeneous catalyst with reduced Brønsted acidity and ionic liquid 1-ethyl-3-methylimidazolium bromide (EMIMBr) to achieve the efficient conversion of high-concentration glucose to HMF. A series of Al-containing materials was synthesized and characterized by N2 adsorption-desorption, XRD, XPS, FIIR, Py-IR and CO2 TPD, among which the Al2O3-b-0.05 prepared by simple alkaline treatment exhibited high Lewis acidity and low Brønsted acidity. The Al2O3-b-0.05 in the medium of EMIMBr leaded to the highest HMF yield of 49.7% from high-concentration glucose (up to 10 wt%), as is more efficient than the heterogeneous EMIMCl/Al2O3-b-0.05 and homogeneous EMIMBr/AlCl3 system. This work provides a paradigm of improving HMF production efficiency via the combined use of heterogeneous Lewis acid catalyst and ionic liquid.
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 楼主| 发表于 2019-4-19 21:41:23 | 显示全部楼层
材料科学与工程学院高学平课题组Advanced Functional Materials,通讯作者:高学平
Advanced Functional Materials Early View First published: 08 April 2019 10.1002/adfm.201901051
https://onlinelibrary.wiley.com/doi/10.1002/adfm.201901051

Conductive CoOOH as Carbon-Free Sulfur Immobilizer to Fabricate Sulfur-Based Composite for Lithium–Sulfur Battery
Zhen-Yu Wang, Lu Wang, Sheng Liu, Guo-Ran Li, and Xue-Ping Gao*
Institute of New Energy Material Chemistry, School of Materials Science and Engineering, Renewable Energy Conversion and Storage Center, Nankai University, Tianjin 300350, China
E-mail: xpgao@nankai.edu.cn

Abstract

Lithium–sulfur battery is recognized as one of the most promising energy storage devices, while the application and commercialization are severely hindered by both the practical gra-vimetric and volumetric energy densities due to the low sulfur content and tap density with lightweight and nonpolar porous carbon materials as sulfur host. Herein, for the first time, conductive CoOOH sheets are introduced as carbon‐free sulfur immobilizer to fabricate sulfur‐based composite as cathode for lithium–sulfur battery. CoOOH sheet is not only a good sulfur‐loading matrix with high electron conductivity, but also exhibits outstanding electrocatalytic activity for the conversion of soluble lithium polysulfide. With an ultrahigh sulfur content of 91.8 wt% and a tap density of 1.26 g cm−3, the sulfur/CoOOH composite delivers high gra-vimetric capacity and volumetric capacity of 1199.4 mAh g−1‐composite and 1511.3 mAh cm−3 at 0.1C rate, respectively. Meanwhile, the sulfur‐based composite presents satisfactory cycle stability with a slow capacity decay rate of 0.09% per cycle within 500 cycles at 1C rate, thanks to the strong interaction between CoOOH and soluble polysulfides. This work provides a new strategy to realize the combination of gra-vimetric energy density, volumetric energy density, and good electrochemical performance of lithium–sulfur battery.
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 楼主| 发表于 2019-4-19 21:41:44 | 显示全部楼层
材料科学与工程学院杜亚平教授Coordination Chemistry Reviews,通讯作者:杜亚平
Coordination Chemistry Reviews, Volume 390, 1 July 2019, Pages 32-49
https://www.sciencedirect.com/sc ... i/S0010854519300839

Rare earth incorporated electrode materials for advanced energy storage
Hongyang Zhao ab, Jiale Xia ab, Dandan Yin ab, Meng Luo ab, ChunhuaYan acd, Yaping Du a*
a Tianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, School of Materials Science and Engineering & National Institute for Advanced Materials, Nankai University, Tianjin 300350, PR China
b Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710000, PR China
c Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, PKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
d College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, PR China
* Corresponding author.
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 楼主| 发表于 2019-4-19 21:42:02 | 显示全部楼层
化学学院赵斌教授Coordination Chemistry Reviews,通讯作者:赵斌
Coordination Chemistry Reviews, Volume 390, 1 July 2019, Pages 50-75
https://www.sciencedirect.com/sc ... i/S0010854518306131


Applications of MOFs: Recent advances in photocatalytic hydrogen production from water
Ying Shi, An-Fei Yang, Chun-Shuai Cao, Bin Zhao*
Department of Chemistry, Key Laboratory of Advanced Energy Material Chemistry, Nankai University, Tianjin 300071, China
*Corresponding author.

Abstract

Owing to the structural controllability, pore modification and unique semiconductor property of metal-organic frameworks (MOFs), the investigation on MOFs as efficient photocatalysts for hydrogen production from water splitting under UV, visible or even NIR light irradiation ha-ve made great progress. In this review, we systematically summarized the recent advances of MOFs-based photocatalysts for hydrogen production from water, and divided them into three categories: MOFs, MOFs composites and MOFs-derived photocatalysts. The high hydrogen production efficiency and possible hydrogen production mechanism of MOFs-based photocatalysts were analyzed in detail. A brief perspective was given to achieve high effective and stable MOFs-based materials for photolysis of water, providing suggestions to explore new and efficient MOFs-based photocatalysts.
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